Yes, the hub is identical
Same 5x120 PCD and same 66.9 mm centre bore: wheels from Buick Envision bolt on and centre on Cadillac CT5 without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Buick Envision is compared with the one from Cadillac CT5 of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈7.5Jx18 ET37 · 235/55R18 — Check on the car
Compared with the original ≈7.5Jx18 ET32 on Cadillac CT5: shock absorber side +5 mm, wheel arch side −5 mm, tyre diameter +5.6 % : fit it with the original tyre size of Cadillac CT5 (245/45R18), not that of Buick Envision.
Comparison for guidance only (estimated width). Check in detail
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Cadillac CT5 (Ecrous - 14x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Cadillac CT5 on Buick Envision?