Yes, the hub is identical
Same 5x114.3 PCD and same 71.6 mm centre bore: wheels from Dodge Grand Caravan bolt on and centre on Jeep Liberty without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Dodge Grand Caravan is compared with the one from Jeep Liberty of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈7Jx16 ET40 · 225/65R16 — Fits like the original
Compared with the original ≈7.5Jx16 ET42 on Jeep Liberty: shock absorber side −8.4 mm, wheel arch side −4.4 mm, tyre diameter −5 % : fit it with the original tyre size of Jeep Liberty (235/70R16), not that of Dodge Grand Caravan.
Comparison for guidance only (estimated width). Check in detail
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≈7Jx15 ET40 · 215/70R15
Jeep Liberty has no 15-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Jeep Liberty (Ecrous - 1/2 - 20 UN), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Jeep Liberty on Dodge Grand Caravan?