Yes, the hub is identical
Same 5x112 PCD and same 57.1 mm centre bore: wheels from McLaren 720S bolt on and centre on Ford Explorer EV without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from McLaren 720S is compared with the one from Ford Explorer EV of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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9Jx19 ET41.65 · 245/35R19 — Risk of rubbing
Compared with the original 8Jx19 ET45 on Ford Explorer EV: shock absorber side +9.3 mm, wheel arch side +16.1 mm, tyre diameter −11.7 % : fit it with the original tyre size of Ford Explorer EV (235/55R19), not that of McLaren 720S.
Check in detail
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Ford Explorer EV (M14x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Ford Explorer EV on McLaren 720S?