Yes, with hub centric rings
Same 5x114.3 PCD, but the centre bore of the wheels from Mitsubishi Outlander (67.1 mm) is larger than the hub of Renault Megane E-Tech (66.1 mm): you need 4 hub centric rings 67.1 → 66.1.
Rings 67.1 → 66.1
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Mitsubishi Outlander is compared with the one from Renault Megane E-Tech of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈7.5Jx18 ET35 · 235/60R18 — Check on the car
Compared with the original 6.5Jx18 ET38 on Renault Megane E-Tech: shock absorber side +9.7 mm, wheel arch side +15.7 mm, tyre diameter +6.9 % : fit it with the original tyre size of Renault Megane E-Tech (195/60R18), not that of Mitsubishi Outlander.
Comparison for guidance only (estimated width). Check in detail
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≈7Jx16 ET38 · 215/70R16
Renault Megane E-Tech has no 16-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Renault Megane E-Tech (M12x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Renault Megane E-Tech on Mitsubishi Outlander?