Yes, the hub is identical
Same 5x130 PCD and same 78.1 mm centre bore: wheels from Peugeot Boxer Maxi bolt on and centre on Maxus EV80 Plus without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Peugeot Boxer Maxi is compared with the one from Maxus EV80 Plus of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈7Jx16 ET68 · 215/75R16 — Check on the car
Compared with the original ≈6Jx16 ET66 on Maxus EV80 Plus: shock absorber side +14.7 mm, wheel arch side +10.7 mm, tyre diameter +4.3 % : fit it with the original tyre size of Maxus EV80 Plus (195/75R16), not that of Peugeot Boxer Maxi.
Comparison for guidance only (estimated width). Check in detail
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Maxus EV80 Plus (M14x1.25), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Maxus EV80 Plus on Peugeot Boxer Maxi?