Yes, the hub is identical
Same 5x108 PCD and same 65.1 mm centre bore: wheels from Volvo V90 bolt on and centre on Volvo S70 without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Volvo V90 is compared with the one from Volvo S70 of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈6.5Jx15 ET43 · 205/60R15 — Check on the car
Compared with the original ≈6Jx15 ET43 on Volvo S70: shock absorber side +6.4 mm, wheel arch side +6.4 mm, tyre diameter +0.9 %.
Comparison for guidance only (estimated width). Check in detail
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≈7Jx17 ET47 · 225/55R17
Volvo S70 has no 17-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Volvo S70 (M12x1.75), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Volvo S70 on Volvo V90?