Yes, the hub is identical
Same 4x100 PCD and same 54.1 mm centre bore: wheels from Hyundai i10 III bolt on and centre on Peugeot 108 without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Hyundai i10 III is compared with the one from Peugeot 108 of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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5.5Jx14 ET42 · 175/65R14 — Risk of rubbing
Compared with the original 4.5Jx14 ET35 on Peugeot 108: shock absorber side +19.7 mm, wheel arch side +5.7 mm, tyre diameter +2.3 % : fit it with the original tyre size of Peugeot 108 (165/65R14), not that of Hyundai i10 III.
Check in detail
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6Jx15 ET48 · 185/55R15
Peugeot 108 has no 15-inch original wheel in our data: check the approved fitments and caliper clearance.
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6.5Jx16 ET48 · 195/45R16
Peugeot 108 has no 16-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Peugeot 108 (M12x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Peugeot 108 on Hyundai i10 III?