Yes, the hub is identical
Same 5x108 PCD and same 63.4 mm centre bore: wheels from Jaguar X-Type bolt on and centre on Jaguar XF Serie without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Jaguar X-Type is compared with the one from Jaguar XF Serie of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈7Jx17 ET60 · 225/45R17 — Check on the car
Compared with the original ≈7.5Jx17 ET49 on Jaguar XF Serie: shock absorber side +4.6 mm, wheel arch side −17.4 mm, tyre diameter −8.1 % : fit it with the original tyre size of Jaguar XF Serie (235/55R17), not that of Jaguar X-Type.
Comparison for guidance only (estimated width). Check in detail
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≈6.5Jx16 ET52.5 · 205/55R16
Jaguar XF Serie has no 16-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Jaguar XF Serie (Ecrous - 12x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Jaguar XF Serie on Jaguar X-Type?