Yes, the hub is identical
Same 5x114.3 PCD and same 66.1 mm centre bore: wheels from Mercedes Citan bolt on and centre on Nissan e-NV200 without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Mercedes Citan is compared with the one from Nissan e-NV200 of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈6Jx15 ET38 · 195/65R15 — Check on the car
Compared with the original 6Jx15 ET45 on Nissan e-NV200: shock absorber side −7 mm, wheel arch side +7 mm, tyre diameter +2.1 % : fit it with the original tyre size of Nissan e-NV200 (185/65R15), not that of Mercedes Citan.
Comparison for guidance only (estimated width). Check in detail
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5.5Jx14 ET44 · 185/70R14
Nissan e-NV200 has no 14-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Nissan e-NV200 (Ecrous - 12x1.25), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Nissan e-NV200 on Mercedes Citan?