Yes, the hub is identical
Same 5x114.3 PCD and same 66.1 mm centre bore: wheels from Mitsubishi Outlander IV bolt on and centre on Renault 5 E-Tech without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Mitsubishi Outlander IV is compared with the one from Renault 5 E-Tech of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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7.5Jx18 ET35 · 235/60R18 — Check on the car
Compared with the original ≈6Jx18 ET38 on Renault 5 E-Tech: shock absorber side +16.1 mm, wheel arch side +22.1 mm, tyre diameter +10 % : fit it with the original tyre size of Renault 5 E-Tech (195/55R18), not that of Mitsubishi Outlander IV.
Comparison for guidance only (estimated width). Check in detail
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8Jx20 ET35 · 255/45R20
Renault 5 E-Tech has no 20-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Renault 5 E-Tech (M12x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Renault 5 E-Tech on Mitsubishi Outlander IV?