Yes, the hub is identical
Same 5x112 PCD and same 57.1 mm centre bore: wheels from Skoda Superb IV bolt on and centre on Skoda Octavia II without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Skoda Superb IV is compared with the one from Skoda Octavia II of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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7.5Jx17 ET41 · 215/55R17 — Risk of rubbing
Compared with the original 7Jx17 ET54 on Skoda Octavia II: shock absorber side −6.6 mm, wheel arch side +19.4 mm, tyre diameter +5.4 % : fit it with the original tyre size of Skoda Octavia II (225/45R17), not that of Skoda Superb IV.
Check in detail
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8Jx18 ET44 · 235/45R18
Skoda Octavia II has no 18-inch original wheel in our data: check the approved fitments and caliper clearance.
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8Jx19 ET44 · 235/40R19
Skoda Octavia II has no 19-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Skoda Octavia II (M14x1.5), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Skoda Octavia II on Skoda Superb IV?