Yes, the hub is identical
Same 5x108 PCD and same 65.1 mm centre bore: wheels from Citroen Jumpy bolt on and centre on Volvo 240 Serie without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Citroen Jumpy is compared with the one from Volvo 240 Serie of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈6Jx14 ET31 · 195/70R14 — Check on the car
Compared with the original ≈6Jx14 ET25 on Volvo 240 Serie: shock absorber side +6 mm, wheel arch side −6 mm, tyre diameter +2.3 % : fit it with the original tyre size of Volvo 240 Serie (185/70R14), not that of Citroen Jumpy.
Comparison for guidance only (estimated width). Check in detail
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≈7Jx15 ET38 · 215/65R15
Volvo 240 Serie has no 15-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Volvo 240 Serie (M1/2 - 20 UNF), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Volvo 240 Serie on Citroen Jumpy?