Yes, the hub is identical
Same 5x108 PCD and same 65.1 mm centre bore: wheels from Citroen Jumpy bolt on and centre on Volvo 745 without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Citroen Jumpy is compared with the one from Volvo 745 of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈6Jx14 ET31 · 195/70R14 — Check on the car
Compared with the original ≈6Jx14 ET25 on Volvo 745: shock absorber side +6 mm, wheel arch side −6 mm, tyre diameter +2.3 % : fit it with the original tyre size of Volvo 745 (185/70R14), not that of Citroen Jumpy.
Comparison for guidance only (estimated width). Check in detail
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≈7Jx15 ET38 · 215/65R15
Volvo 745 has no 15-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Volvo 745 (M12x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Volvo 745 on Citroen Jumpy?