Yes, the hub is identical
Same 6x130 PCD and same 84.1 mm centre bore: wheels from Volkswagen Crafter 30,35 bolt on and centre on Mercedes eSprinter without rings. You still need to check the offset and tyres, detailed below.
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Volkswagen Crafter 30,35 is compared with the one from Mercedes eSprinter of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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5.5Jx16 ET51 · 205/75R16 — Risk of rubbing
Compared with the original 5.5Jx16 ET117 on Mercedes eSprinter: shock absorber side −66 mm, wheel arch side +66 mm, tyre diameter +0 %.
Check in detail
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Mercedes eSprinter (M14x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Mercedes eSprinter on Volkswagen Crafter 30,35?