Yes, with hub centric rings
Same 5x108 PCD, but the centre bore of the wheels from Mercedes Citan (66.1 mm) is larger than the hub of Nissan NV250 (60.1 mm): you need 4 hub centric rings 66.1 → 60.1.
Rings 66.1 → 60.1
≈: width estimated from the original tyre size.
Wheel by wheel: offset and tyres
Each original wheel from Mercedes Citan is compared with the one from Nissan NV250 of the same diameter: how much closer the wheel gets to the shock absorber or how far it sticks out of the wheel arch, and whether the tyre keeps the same overall diameter.
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≈6Jx15 ET38 · 195/65R15 — Check on the car
Compared with the original 6Jx15 ET44 on Nissan NV250: shock absorber side −6 mm, wheel arch side +6 mm, tyre diameter +0 %.
Comparison for guidance only (estimated width). Check in detail
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5.5Jx14 ET44 · 185/70R14
Nissan NV250 has no 14-inch original wheel in our data: check the approved fitments and caliper clearance.
Before fitting the wheels
An identical hub is not enough: offset, width and diameter change the position of the wheel, and larger calipers can touch a smaller wheel. Original wheels often use bolts or nuts with a specific seat: keep the fixings intended for the wheel, with the thread of Nissan NV250 (M12x1.50), tightened to the torque shown on its vehicle page. Finally, check that the size is among the approved fitments for your vehicle. This comparison is for guidance only: have the fitting approved by a professional.
And the other way round: wheels from Nissan NV250 on Mercedes Citan?